“…The absorption profile showed the tail in the long wavelength region (> 360 nm), which was much reduced in the PLE profile. Accordingly, the absorbance in the long wavelength region was ascribed to the involvement of trapped states, 42,43 which were responsible for the excitation-dependent PL spectra by the intragap excitation. Besides, the reduced intensity suggested the low emission efficiency of trapped states (< 5%), 20 because the absorbance in the long wavelength region indicated the nontrivial density of trapped states.…”
Three types of carbon dots (CDs) are synthesized from isomers of phenylenediamine to develop multicolor nanomaterials with low toxicity, high stability, and high quantum yield. The distinctive electronic structures of...
“…The absorption profile showed the tail in the long wavelength region (> 360 nm), which was much reduced in the PLE profile. Accordingly, the absorbance in the long wavelength region was ascribed to the involvement of trapped states, 42,43 which were responsible for the excitation-dependent PL spectra by the intragap excitation. Besides, the reduced intensity suggested the low emission efficiency of trapped states (< 5%), 20 because the absorbance in the long wavelength region indicated the nontrivial density of trapped states.…”
Three types of carbon dots (CDs) are synthesized from isomers of phenylenediamine to develop multicolor nanomaterials with low toxicity, high stability, and high quantum yield. The distinctive electronic structures of...
“…In general, the steeper the slope, or more quantitatively, the smaller the Urbach energy, the higher the crystallinity and homogeneity. 22 The Urbach energy of ZnO and Mg:ZnO single films is less than 100 meV (Fig. S3 and S4 †); and their band gaps were uniform to be 3.3 eV and 3.9 eV, respectively.…”
Section: Catalysis Science and Technology Papermentioning
The impact of band gap-graded structures artificially implemented in a photocatalyst on the photoelectrochemical properties was investigated in a model system of epitaxial thin film Mg-ZnO. The band gap-graded Mg-ZnO...
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