Sorghum is a plant that produces syrup, forage and animal feed silage. The utilization of sorghum stalk as fuel oil (bioethanol) is an energy increasingly needed by the depletion of deposits of fossil fuel oil. Thus, tools and methods are needed to produce sorghum stem bioethanol, which has a certain purity level. This study aims to increase the purity of bioethanol from sorghum stems using the Bernoulli Distillation System (BDS) by experimentally testing the purification of sorghum stem bioethanol. In the bioethanol purification stage, heat transfer in the reactor and condenser was analyzed, and the performance of the ejector was analyzed with a vacuum pressure (-55 cmHg), temperature 71°C, test time of 1800, 3600, 5400 and 7200 seconds with a test material of 28% capacity 20 liters. The results of the analysis of the highest conduction heat transfer on the water jacket wall are 14757.72 Joules, the reactor tank is 962.1 Joules, the bottom of the reactor tank is 765.05 Joules and convection in the reactor fluid is 2.09 Joules. The highest heat transfer energy in the condenser is 72683.1 Joules. While the efficiency of the water jet ejector is 65.4%, the highest increase in bioethanol content is 51% in 3600 seconds, as much as 745 ml. The characteristics of the bioethanol obtained included a calorific value test of 1389.48 cal/gram, a viscosity of 1.02044, a flash point of 32.5°C, and a density of 0.934 g/cm3. Thus, the Bernoulli Distillation System’s purification process can increase bioethanol levels effectively and efficiently.