This work focuses on developing a
dynamic model of a packed bed
column for biodiesel washing. Its development was motivated by increasing
problems in these columns when higher amounts of waste cooking oil
and other low-quality fatty materials are incorporated as raw materials.
This incorporation causes the formulations of raw oil to change significantly,
requiring process flexibility and adequate control systems to maintain
the product within strict quality standards and prevent operational
problems. A detailed rate-based model of a packed column is implemented
in gPROMS ModelBuilder, accounting for mass transfer and hydrodynamics
phenomena such as holdup, flooding, and phase inversion. The model
is compared to data from an industrial unit. The simulation results
are in good agreement with the typical concentration values measured
in the industrial unit. Using the developed model, the influence of
operating parameters and the presence of contamination on the column’s
behavior are studied.