Profitable Fischer Tropsch realization via CO2–CH4 reforming; an overview of nickel–promoter–support interactions

Alhassan, M.; Jalil, Aishah Abdul; Bahari, Mahadi B.; Owgi, A.H.K.; Nabgan, Walid; Hassan, N.S.; Tran, Thuan Van; Abdul-Rahman, Alias; Hamid, M.Y.S.; Ikram, Muhammad; Firmansyah, M.L.; Holilah, Holilah; Sholeha, Novia Amalia

doi:10.1039/d2ra06773k

Cited by 13 publications

(4 citation statements)

References 118 publications

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“…63 Those conditions can vary based on obtaining desired products including wax, diesel, aviation fuels and light hydrocarbons. Transition metals such as Fe, 64,65 Co, 66,67 and Ni, 68 are extensively studied in F-T reactions.…”

Section: Co 2 Utilization Pathways For Decarbonization Of Power and I...mentioning

confidence: 99%

Assessing various CO₂ utilization technologies: a brief comparative review

Turakulov,

Kamolov,

Norkobilov

et al. 2024

J of Chemical Tech & Biotech

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Carbon dioxide (CO2) utilization technologies have emerged as a promising approach to address the direct and indirect consequences of climate change and the need for sustainable resource management. Those innovative technologies aim to capture and utilize CO2 by converting it into valuable products or directly using it as a chemical feedstock in various industries, thus, avoiding their release into the atmosphere. In this study, different CO2 utilization pathways including CO2 to chemicals and fuels, CO2 to building materials, CO2 to enhanced oil recovery (EOR), and CO2 to bio‐products are discussed in terms of their status ‐ economical, environmental, and technology readiness level performances. Moreover, various CO2 utilization pathways are comparatively analyzed considering their advantages and drawbacks, CO2 uptake potentials, and overall climate benefits. According to the comparison results, photocatalytic and electrochemical reduction of CO2 along with the bio‐fixation of CO2 are gaining more attention in the recent research and investigations from the energy intensity and environmental point of view, while EOR still dominant in terms of the scalability, maturity, and economical benefits. However, limitations of EOR related to the capacity, life cycle, and different geolocations, as well as the complexities of other mature approaches make room for emerging technologies to be more energy‐effective and environmentally friendly. Overall, most of the promising CO2 utilization techniques are either technologically immature or limited in scale to deploy globally. One of the main barriers to reusing CO2 is associated with the high cost of CO2‐based production and the low value of the CO2 market.This article is protected by copyright. All rights reserved.

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Section: Co 2 Utilization Pathways For Decarbonization Of Power and I...mentioning

confidence: 99%

Assessing various CO₂ utilization technologies: a brief comparative review

Turakulov,

Kamolov,

Norkobilov

et al. 2024

J of Chemical Tech & Biotech

View full text Add to dashboard Cite

show abstract

“…Additionally, metal-support interactions between the non-noble metal and the catalyst support can significantly influence catalyst performance. Strong metal-support interactions can stabilize the metal particles, enhancing catalyst stability and preventing sintering to some extent [2]. However, excessively strong interactions can also reduce the mobility of metal species on the support, limiting their ability to participate in the catalytic reaction.…”

Section: Challenges Of Non-noble Metal Catalystsmentioning

confidence: 99%

“…In the context of the growing global energy demand and concerns about climate change, the development of sustainable and environmentally friendly technologies for energy conversion and production is of paramount importance [1]. One such technology gaining attention is the dry reforming of methane (DRM), a process that converts methane (CH4) and carbon dioxide (CO2) into syngas, a valuable mixture of hydrogen (H2) and carbon monoxide (CO) [2]. Syngas is a versatile feedstock for various industrial processes, including the synthesis of liquid fuels, chemicals, and energy generation.…”

Section: Introductionmentioning

confidence: 99%

“…In the field of methane conversion, various technologies have been created, each with specific purposes. One of these technologies is steam reforming, which is commonly used but not suitable for the Fischer-Tropsch (FT) process because it requires changes to the H2/CO ratio [2,5]. On the contrary, autothermal reforming allows for adjusting this ratio, but it produces less hydrogen and requires careful control and significant energy [6].…”

Section: Introductionmentioning

confidence: 99%

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Non-noble metal catalysts for dry reforming of methane: Challenges, opportunities, and future directions

Alhassan,

Bin Bahari,

Hamad Khalifa Owgi

et al. 2024

E3S Web Conf.

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The utilization of non-noble metal catalysts for the dry reforming of methane (DRM) has gained significant attention in recent years due to the increasing demand for clean and sustainable energy sources. DRM involves the conversion of methane (CH4) and carbon (IV) oxide (CO2) into synthesis gas (syngas), a valuable mixture of hydrogen (H2) and carbon monoxide (CO). Commercialization of non-noble metal catalysts for this reaction presents several challenges that must be addressed to achieve practical implementation. This short review discusses the challenges, opportunities, and future directions of non-noble metal catalysts for DRM. First, the limitations associated with the intrinsic activity and stability of non-noble metals, such as nickel, cobalt, and iron, are explored. Enhancing catalyst performance through compositional modifications, the incorporation of promoters and supports, are ways to overcome these challenges. Directions that hold promise for advancing non-noble metal catalysts in DRM, including the advanced exploration of bimetallic catalysts for synergistic effects, and the integration of non-noble metals into novel catalytic systems, were among the future proposals, while non-noble metal catalysts have the potential to revolutionize the production of syngas and contribute significantly to the transition towards sustainable energy solutions.

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Silica-Based Materials in Methane Conversion: A Two-Decade Bibliometric and Literature Review (1995–2022)

Alhassan,

Jalil,

Omoregie

et al. 2024

Top Catal

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Profitable Fischer Tropsch realization via CO₂–CH₄ reforming; an overview of nickel–promoter–support interactions

Abstract: Particle size increases during agglomeration, which causes catalyst deactivation. Reducible metal oxide restricts metal growth, hence reducing the sintering.

Cited by 13 publications

References 118 publications

Assessing various CO₂ utilization technologies: a brief comparative review

Assessing various CO₂ utilization technologies: a brief comparative review

Non-noble metal catalysts for dry reforming of methane: Challenges, opportunities, and future directions

Silica-Based Materials in Methane Conversion: A Two-Decade Bibliometric and Literature Review (1995–2022)

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Profitable Fischer Tropsch realization via CO2–CH4 reforming; an overview of nickel–promoter–support interactions

Abstract: Particle size increases during agglomeration, which causes catalyst deactivation. Reducible metal oxide restricts metal growth, hence reducing the sintering.

Cited by 13 publications

References 118 publications

Assessing various CO2 utilization technologies: a brief comparative review

Assessing various CO2 utilization technologies: a brief comparative review

Non-noble metal catalysts for dry reforming of methane: Challenges, opportunities, and future directions

Silica-Based Materials in Methane Conversion: A Two-Decade Bibliometric and Literature Review (1995–2022)

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Product

Resources

About

Profitable Fischer Tropsch realization via CO₂–CH₄ reforming; an overview of nickel–promoter–support interactions

Assessing various CO₂ utilization technologies: a brief comparative review

Assessing various CO₂ utilization technologies: a brief comparative review