Inkjet printing of high-viscosity (up to 105 mPa·s) nanosilver inks is an interesting emerging technology to achieve the 3D fully printed fabrication of electronic products. The highly viscous force of the ink makes it impossible to achieve droplet ejection with the traditional piezoelectric-driven drop-on-demand inkjet method. In this study, a pneumatic needle jetting valve is adopted to provide sufficient driving force. A large number of high-viscosity inkjet printing tests are carried out, and the jetting behavior is recorded with a high-speed camera. Different jetting states are determined according to the recorded images, and the causes of their formation are revealed. Additionally, the effects of the operating pressure, preload angle, and fluid pressure on jetting states are elucidated. Furthermore, the jetting phase diagram is obtained with the characterization of the Reynolds number and the printable region is clarified. This provides a better understanding of high-viscosity inkjet printing and will promote the application of high-viscosity inkjet printing in 3D fully printed electronic products.