2010
DOI: 10.3390/ma3053141
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Progress of Multi Functional Properties of Organic-Inorganic Hybrid System, A[FeIIFeIIIX3] (A = (n-CnH2n+1)4N, Spiropyran; X = C2O2S2, C2OS3, C2O3S)

Abstract: In the case of mixed-valence systems whose spin states are situated in the spin crossover region, new types of conjugated phenomena coupled with spin and charge are expected. From this viewpoint, we have investigated the multifunctional properties coupled with spin, charge and photon for the organic-inorganic hybrid system, A[FeIIFeIIIX3](A = (n-CnH2n+1)4N, spiropyran; X = dto(C2O2S2), tto(C2OS3), mto(C2O3S)). A[FeIIFeIII(dto)3] and A[FeIIFeIII(tto)3] undergo the ferromagnetic phase transitions, while A[FeIIFe… Show more

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Cited by 8 publications
(3 citation statements)
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References 77 publications
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“…Among them, only [( n -C 4 H 9 ) 4 N][Fe III Fe II (dto) 3 ] exhibits charge transfer phase transition, whereas the other two compounds with n = 5 and 6 don't show such phase transitions. 70 …”
Section: Electronic Ferroelectricsmentioning
confidence: 99%
See 1 more Smart Citation
“…Among them, only [( n -C 4 H 9 ) 4 N][Fe III Fe II (dto) 3 ] exhibits charge transfer phase transition, whereas the other two compounds with n = 5 and 6 don't show such phase transitions. 70 …”
Section: Electronic Ferroelectricsmentioning
confidence: 99%
“…Thus, [(n-C 3 H 7 ) 4 N] [Fe III Fe II (dto) 3 ] has received attention owing to its molecular [Fe III Fe II (dto) 3 ] exhibits charge transfer phase transition, whereas the other two compounds with n = 5 and 6 don't show such phase transitions. 70 Recently, the electric polarization properties of [(n-C 3 H 7 ) 4 N] [Fe III Fe II (dto) 3 ] have been investigated in depth. The P-E curve of a lm of [(n-C 3 H 7 ) 4 N][Fe III Fe II (dto) 3 ] measured at 300 K shows a clear polarization hysteresis in the in-plane direction (Fig.…”
Section: [(N-c 3 H 7 ) 4 N][fe III Fe Ii (Dto) 3 ]mentioning
confidence: 99%
“…The hybrid materials have broad potential applications as nano llers. 21,22 Methods to synthesize inorganic-organic hybrid materials are oen based on so chemistry approaches, such as sol-gel process, intercalation, exchange, or graing. Benzenephosphinic acid (BPA) is not applied in PLA as an additive ame retardant because the carboxyl group in BPA could react with PLA during melt processing and in use, which results in the depolymerization of PLA molecules and the deterioration to the performances of the PLA composites such as mechanical properties.…”
Section: Introductionmentioning
confidence: 99%