Ten types ¢-type titanium alloys for as-cast applications were proposed by using mainly ubiquitous elements in the area greatly differ from conventional alloys in compositions, in the diagram consisting of bond order (Bo) and d-orbital energy level (Md). The object was to develop ¢type titanium alloys with ultimate tensile strength value of 1000 MPa and fracture strain value of 10% in as-cast condition without the posttreatments after cold crucible levitation melting, and their microstructures were controlled by adjusting its process parameters. The same microstructure and mechanical properties were also indicated on both as-cast and solution treated alloys, which mean the unnecessary of solution treatment in proposed alloys. Ti5.2Cr5.5Mn2.2Fe5.5Zr, Ti11Cr6Mn4.5Zr0.5Al and Ti13Zr6Mn6Cr5V alloys with a ¢ mono phase achieved objective values of mechanical properties in as-cast condition, which lead to development of alternative materials to the conventional ¢type titanium alloys, since they reduce energy consumption and 25% production costs by omitting complex post processing procedures. Moreover, the phase boundary between the mono ¢ phase and dual ¢ plus intermetallic compound phases were predicted for the first time in ¢type titanium alloys, according to the ten proposed alloys in newly expanded compositional area of the Bo t -Md t diagram.