SiC/Al composites are widely used in aerospace and other fields due to their excellent mechanical properties. For large-concentration composites, due to the extremely high proportion of SiC and the unstable interface between the two phases, the SiC particles are broken and detached during the processing, which makes the surface quality of the workpiece insufficient to meet the service requirements. Electrically assisted cutting technology is expected to break through this technical bottleneck. This paper investigates the surface quality of high-concentration SiC/Al grinding with electroassisted biolubricant MQL. The surface morphology after processing is observed. Firstly, by comparing the traditional grinding and electrically assisted grinding conditions, it is found that the fundamental reason for the improvement in the grinding surface quality using a pulse current is the improvement in the Al plasticity. Secondly, based on the thermal effect and non-thermal effect of the pulse current, the influence of the electrical parameters (current, duty cycle and frequency) on the machining indication quality is discussed. It is found that when the current and duty cycle increase, the machining surface quality will also increase, while the frequency change has little effect on the surface quality. Finally, friction and wear experiments are carried out on the grinding surface under different working conditions to explore the friction and wear characteristics of the surface of the workpiece. The results show that the pulse current can significantly improve the wear resistance of the grinding surface.