“…Micron-sized aluminum powders are often added into various energetic materials, including pyrotechnics, explosives, and rocket propellants. It is because that the performance of energetic materials can be highly improved such as the oxidation enthalpy and the combustion temperature, especially the motor acoustic stability [1][2][3][4] In recent several decades, basic understanding of aluminum combustion mechanisms has been improved significantly in experimental and theoretical investigations [5][6][7][8][9]. However, it is difficult to determine the accurate reactive mechanism because the different properties of aluminum powders, for instance, the specific surface area, particle size and distribution, different synthetic methods, environment condition, core@shell structure of aluminum powder [10,11] will eventually influence the oxidation mechanism of aluminum.…”