1992
DOI: 10.1002/pat.1992.220030106
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Properties of block and graft copolymers of polybutadiene with small complexed poly(4‐vinylpyridine) segments

Abstract: Various diblocks, triblocks and a graft copolymer of butadiene with 4‐vinylpyridine short blocks have been prepared. They were complexed with ZnCl2 to give ionomer‐like materials. For all copolymers, the Tg of the elastomeric block (−84°C to −91°C) was unchanged by complexation. For all diblocks and triblocks with short blocks (DPn ∼ 3) the storage modulus was only slightly increased by comparison with uncomplexed materials. For the graft copolymer even with short blocks the material is less sensitive to tempe… Show more

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