The solar wind that flows outward from the Sun through our solar system is primarily composed of ionized hydrogen (protons, ∼95% of the solar wind number density on average), but also contains doubly ionized helium (alpha particles, ∼4%), and an admixture of other heavier ions (∼1%), many multiply charged (Bame et al., 1968;Ogilvie & Coplan, 1995;von Steiger et al., 2000). The relative abundance of alpha particles in the solar wind ranges from <1% to ∼10%, and varies with solar cycle, heliographic latitude, and solar wind speed (Aellig et al., 2001;Kasper et al., 2007).In addition to doubly ionized helium (He ++ ), the solar wind sometimes contains a small amount of singly ionized helium (He + ). This can occur in unusually cold solar plasma (Gosling et al., 1980;Schwenn et al., 1980) such as that sometimes found in coronal mass ejections. He + can also originate from ionization and pickup of interstellar neutral helium (Möbius et al., 1985), which produces a localized signature in the portion of the heliosphere downstream from the interstellar neutral flow, enhanced by the solar gravitational focusing of helium atom trajectories (Gloeckler et al., 2004).The production of He + can also occur in situ, by charge exchange between solar wind He ++ and neutral gases. For example, charge exchange with volatiles in a cometary coma leads to a ratio of singly to doubly ionized helium that increases with decreasing distance to the nucleus, with observations of this ratio thereby enabling reconstruction of the neutral density profile (