The excited level scheme of IS9Os as populated by the decay of 23.4-h IS9Re has been studied by use of Ge(Li) and Si(Li) detectors in the ),-ray singles and coincidence mode. The data confirm the presence of excited levels in 189Os at 30.8 (J~=9/2-), 36.2 (1/2-), 69.5 (5/2-), 95.2 (3/2-), 216.7 (7/2-), 219.4 (7/2-), 233.6 (3/2-), 275.8 (5/2-), 496.8 (1/2-, 3/2 +) and 599.8 (t/2-, 3/2 +) keV. The spin and parity assignments are based on multipolarities determined by internal conversion coefficient measurements and decay systematics. A decay scheme is established for lS9Re which accommodates 98% of the electromagnetic transition intensity. No evidence for the 150-d lS9Re isomer was found in this study.