We examine the role of refractory organics as a major C carrier in the outer protosolar nebula and its implications for the compositions of large Kuiper Belt objects (KBOs) and CI chondrites. By utilizing Rosetta measurements of refractory organics in comet 67P/Churyumov–Gerasimenko, we show that they would make up a large fraction of the protosolar C inventory in the KBO-forming region based on the current widely adopted solar abundances. However, this would free up too much O to form water ice, producing solid material that is not sufficiently rock-rich to explain the uncompressed density of the Pluto–Charon system and other large KBOs; the former has been argued as the most representative value we have for the bulk composition of large KBOs. This inconsistency further highlights the solar abundances problem—an ongoing challenge in reconciling spectroscopically determined heavy-element abundances with helioseismology constraints. By employing a new data set from solar CNO neutrinos and solar wind measurements of C, N, and O, we show that the uncompressed density of the Pluto–Charon system can be reproduced over a wide range of scenarios. We show that a lack of sulfates in Ryugu and Bennu samples implies a lower amount of water ice initially accreted into CI chondrite parent bodies than previously thought. These data are found to be consistent with the solar C/O ratio implied by the new data set. Our predictions can be tested by future neutrino, helioseismology, and cosmochemical measurements.