The interposer or fan-out packaging technology with ultra-fine line/space and high frequency signal has been required in order to achieve high speed interconnection between chips with low cost. In this paper, we have newly developed low Dk and Df photosensitive insulation material. The additional features of the developed materials are very low moisture absorptivity less than 0.3 wt%, low anion impurities and high resistance to hydrolysis. The micro-strip line was fabricated to evaluate the influence of developed material. The insertion loss from transmission lines on Material C shows much lower loss than the conventional reference material at higher frequencies. The peel strength to the sputtered Ti and Cu is over 0.7 kN/m. The material also demonstrated SAP fabrication compatibility with fine circuitry and passed insulation reliability by biased-HAST showing no copper migration measured by EDX.