In order to solve the problems of highway traffic congestion and frequent traffic accidents, a technology method for highway information collection, processing, and control based on RFID Internet of Things is proposed. The highway information collection and processing control technology designed in this paper is based on radio frequency identification technology to realize the collection of highway vehicle information, analyze, and process the collected information, and finally get the road condition information. Through the extraction and analysis of the traffic flow information in the video surveillance, the background difference method is used to extract the relevant vehicle factors in the video, including the extraction of traffic flow information, vehicle model extraction, and vehicle speed extraction. Traffic detection provides convenience. The experimental data shows that from Monday to Friday on weekdays, the road congestion rates are 2.72%, 1.94%, 2.77%, 2.27%, and 3.47% respectively; the average vehicle speed on weekdays is 89.96 km/h, and the test results are fast and accurate. The proposed method integrates road information collection and road information service, realizes traffic detection when there are vehicles, and realizes detection and perception of large-scale road traffic systems. Travelers provide real-time traffic information and navigation services.