Quantification of mass fractions. The mass fraction of each compound on the FID (W i) was calculated using the mass fraction of the internal standard (W st), peak volumes obtained from the GC × GC-FID and the response factor relative to methane. ܹ = ݂ ܸ ݂ ௦௧ ܸ ௦௧ ܹ ௦௧ (1) where f i is the relative response factor for compound i, V i is the peak volume of compound i, f st is the relative response factor of the internal standard and V st is the peak volume of the internal standard. The response factor of each component is calculated based on the effective carbon number as follows 1, 2 : ݂ = ܯ ܯ ுସ ܰ , (2) Table S1. Comparison between elemental carbon hydrogen and oxygen quantified by GC × GC-FID/TOF-MS analysis.