Epoxidized natural
rubber (ENR) offers a unique combination of
strength, sustainability, and versatile structure, making it a good
candidate for creating sacrificial and reformable bonds via secondary
curatives. These curatives should be simple and compatible with other
rubber ingredients and industrial mixing processes. Although many
alternative curatives, including zinc chloride, zinc dimethacrylate
(ZDMA), and sebacic acid (SA), have been proven to be successful,
they have never been compared in the same compound. Moreover, the
effectiveness of these alternative curatives on network formation,
including their interactions with the other ingredients of a rubber
compound, such as fillers, coupling agents, and traditional curatives,
has not been fully studied yet. Based on the current study, these
secondary curatives alone cannot provide a sufficient level of vulcanization.
However, adding ZDMA or SA together with sulfur curatives allowed
improving the tensile properties and showed microlevel self-healing
behavior during cyclic loading. The addition of 10 phr (parts per
hundred rubber) ZnCl2 created weak, short, and rigid bonds
in ENR detectable by simple Payne measurements. However, that led
to active interaction with all compounding ingredients and deterioration
of the physical properties. Reducing the ZnCl2 load to
1 phr allowed full recovery of stress after the cyclic test and fair
tensile strength of the compound.