Proton Resonance Studies of Ortho-Substituted Phenols

Abstract

ConclusionElectrode processes with specific adsorption of reactant and/or product can be analyzed rather rigorously by the method of this paper. Further progress requires experimental studies on (a) adsorption isotherms, (b) 591 determination of the standard free energy of adsorption as a function of charge density, and (c) application of the experimental criterion deduced in this paper.Acknowledgment.-This investigation was supported by the National Science Foundation.

Spectroscopic Studies of Hydrogen Bonding

“…4o The formation of cistrans dimers of ortho-halophenols in dilute solution has been studied by Allan and Reeves. 41 The effect of steric hindrance by ortho-substituents on the self-association of phenols has been examined by several workers. 1 7 ,42 ,43 The association shifts in the hindered phenols have been correlated with the size of the substituents.…”