Proton Transfer in Solid State: Mechanochemical Reactions of Imidazole with Metallic Oxides

Fernández‐Bertrán, J.; Castellanos‐Serra, Lila; Yee‐Madeira, H.; Reguera, E.

doi:10.1006/jssc.1999.8417

Cited by 36 publications

(24 citation statements)

References 22 publications

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“…Metal oxides are attractive precursors due to low cost, ready availability, and because the only byproduct is water. Mechanochemical reactivity of metal oxides with organic ligands was explored by Fernandez-Bertran, [289] CoCl 2 (bipy) by LAG of cobalt(II) carbonate with bipyridinium chloride. [288] The product was identical to that obtained by LAG of CoCl 2 and bipy with water.…”

Section: Acid-base Reactionsmentioning

confidence: 99%

Mechanochemistry: opportunities for new and cleaner synthesis

et al. 2012

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Citation for published item:tmesD F vF nd edmsD gF tF nd folmD gF nd frgD hF nd gollierD F nd pri § s § i¡ D F nd qrepioniD pF nd rrrisD uF hF wF nd ryettD qF nd tonesD F nd uresD eF nd wkD tF nd winiD vF nd yrpenD eF qF nd rkinD sF F nd herouseD F gF nd teedD tF F nd ddellD hF gF @PHIPA 9wehnohemistry X opportunities for new nd lener synthesisF9D ghemil soiety reviewsFD RI @IAF ppF RIQERRUF Further information on publisher's website: Use policyThe full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-prot purposes provided that:• a full bibliographic reference is made to the original source • a link is made to the metadata record in DRO • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders.Please consult the full DRO policy for further details.

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Section: Acid-base Reactionsmentioning

confidence: 99%

Mechanochemistry: opportunities for new and cleaner synthesis

et al. 2012

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“…Perhaps the first example of mechanochemical reactivity of metal oxides against organic ligands was reported by Fernández-Bertrán, who obtained coordination polymers of Ag(I), Zn, Cd and Hg(II) by manually grinding the respective metal oxides with imidazole. 70 Analogous reactions with oxides of other transition metals, Pb(II) or Mg could not be achieved, suggesting that the nd 10 configuration of the metal ion was important for the reactivity. Construction of coordination polymers from metal carbonates was utilized in the synthesis of the 2D framework Co(bipy)Cl 2 by LAG of cobalt(II) carbonate with bipyridinium chloride (Figure 7.6a).…”

Section: Synthesis Of Coordination Polymers and Mofs From Metal Oxidementioning

confidence: 97%

Chapter 7. Ball-milling Mechanochemical Synthesis of Coordination Bonds: Discrete Units, Polymers and Porous Materials

Friščić¹

2014

Green Chemistry Series

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“…On the molecule reaction with the metal, the sharp intense band, close to 1055 cm~1, corresponding to a CH bending vibration, shifts to 1085 cm~1. Such spectral changes are sensing the metal coordination by both, the pyridinic and pyrrolic N atoms [22]. Figure 1 shows typical PXRD patterns collected for the series Zn(MIm) 2 , Co(MIm) 2 and Zn 1-x Co x (MIm) 2 .…”

Section: On the Porous Framework Of The Materials Under Studymentioning

confidence: 98%