The
nutrient supply to the oceanic surface water is largely regulated
by the extrinsic and intrinsic ambient atmospheric aerosol properties,
particularly chemistry. In this context, we measured the comprehensive
chemical composition (inorganic ions and major elements) of atmospheric
aerosols and studied their spatial distribution over the Arabian Sea
during the southwest monsoon (SWM) period for 2 consecutive years
(2017 and 2018). We found that the water-soluble ionic concentration
(WSIC) is dominated by Na+ and Cl– ions
followed by Ca2+ and SO4
2– with a minor contribution of Mg2+ and NO3
–. The relative contribution of ionic species to WSIC
remained similar for both the monsoon seasons with higher WSIC during
2018 (69.3 ± 63 μg m–3) compared to 2017
(40.6 ± 33 μg m–3). Sea salt (estimated
from Na+ and Cl– ions) and mineral dust
(calculated from the Al concentration) are dominant constituents of
aerosols, with negligible contribution from anthropogenic species
found to be temporally and spatially consistent during both the campaigns.
The mineral dust is characterized by a uniform Nd isotopic signature
during both campaigns, indicating its source to the Arabian Peninsula
during the study period. Source apportionment of mineral dust using
the Nd isotope is supported by back-trajectory analyses as well as
satellite retrieved (MODIS and CALIPSO) data. The Cl– deficit, which is mainly attributed to the interaction of sea salt
with acidic species, is found to be relatively low (10–12%)
compared to that during continental outflow over the Arabian Sea,
indicating the insignificant contribution from anthropogenic emissions
during the SWM months.