Prussian blue, its analogues and their derived materials for electrochemical energy storage and conversion

Chen, Junsheng; Li, Wei; Mahmood, Asif; Pei, Zengxia; Zhou, Zheng; Chen, Xuncai; Chen, Yuan

doi:10.1016/j.ensm.2019.09.024

Cited by 219 publications

(130 citation statements)

References 225 publications

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“…So far, there have been several review papers on PBAs published, most of which were intended to discuss the broad applications of PBAs and a large number of their derivatives in the area including but not limited to batteries. [ 40–47 ] Chou and co‐workers specifically discussed the potential of PBAs for future NIBs from the aspect of commercialization, [ 39 ] and Yamauchi and co‐workers summarized the nanoarchitectonics of PBAs and their derivatives. [ 48 ] In addition, a perspective on stoichiometry control, water effect, modelling, synthesis and technoeconomics of PBAs was provided by Pasta and co‐workers.…”

Section: Introductionmentioning

confidence: 99%

Hexacyanoferrate‐Type Prussian Blue Analogs: Principles and Advances Toward High‐Performance Sodium and Potassium Ion Batteries

Zhou

Cheng

Wang

et al. 2020

Advanced Energy Materials

295

209

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Na‐ion batteries (NIBs) and K‐ion batteries (KIBs) are promising candidates for next‐generation electric energy storage applications due to their low costs and appreciable energy/power density compared to Li‐ion batteries. In the search for viable electrode materials for NIBs and KIBs, Prussian blue analogs (PBAs) with inherent rigid and open frameworks and large interstitial voids have shown an impressive ability to accommodate big alkali‐metal ions without structure collapse. In particular, hexacyanoferrates (HCFs) utilizing abundant Fe(CN)6 resources are the most interesting subgroup of PBAs, being able to deliver a specific capacity of 70–170 mAh g‒1 and a voltage of 2.5‒3.8 V in NIBs/KIBs. In this Review, a comprehensive discussion of the HCF‐type cathode materials in terms of their structural features, redox mechanisms, synthesis control, and modification strategies based on research advances over the last ten years. The methodologies and achievements in improving the material properties of HCFs including the compositional stoichiometry, crystal water, crystallinity, morphology, and electrical conductivity are outlined, with the aim to promote understanding of these materials and provide new insights into future design of PBAs for advanced rechargeable batteries.

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Section: Introductionmentioning

confidence: 99%

Hexacyanoferrate‐Type Prussian Blue Analogs: Principles and Advances Toward High‐Performance Sodium and Potassium Ion Batteries

Zhou

Cheng

Wang

et al. 2020

Advanced Energy Materials

295

209

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“…Recently, several review/progress on the research of PBAs have been conducted, among which some works focused mainly on applications of PBAs in alkaline‐ion batteries and electrochemical catalysts, [ 19,45,46 ] while others on either the electrochemical performances of PBAs‐derived materials [ 47,48 ] or their crystal structure, synthesis, and working principle in rechargeable batteries. [ 30,49 ] In this work, differing from the previous reviews, we present a novel perspective on the potential application of PBAs and the strategies to optimize them in future energy storage/conversion technologies, after making a detailed summary of the crystal structure and reaction mechanisms of the PBA‐based host materials ( Figure ).…”

Section: Introductionmentioning

confidence: 99%

Structure and Properties of Prussian Blue Analogues in Energy Storage and Conversion Applications

Qin

Shihua

et al. 2020

Adv Funct Materials

315

209

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In recent years, Prussian blue analogue (PBA) materials have been widely explored and investigated in energy storage/conversion fields. Herein, the structure/property correlations of PBA materials as host frameworks for various charge‐carrier ions (e.g., Na+, K+, Zn2+, Mg2+, Ca2+, and Al3+) is reviewed, and the optimization strategies to achieve advanced performance of PBA electrodes are highlighted. Prospects for further applications of PBA materials in proton, ammonium‐ion, and multivalent‐ion batteries are summarized, with extra attention given to the selection of anode materials and electrolytes for practical implementation. This work provides a comprehensive understanding of PBA materials, and will serve as a guidance for future research and development of PBA electrodes.

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“…The R-PB shows better cycling performance at a high current density of 5 C that the capacity maintains at 70.25 % even after 3500 cycles, corresponding to the capacity fading rate of only 0.85 % per 100 cycles and 5.96 % per 100 cycles at 1 C. Bene ting from a well-controlled co-precipitation process in the acid solution, the R-PB shows low-vacancy concentration and suppressed crystal water content, leading to high ICE, enhanced cycle and rate performance 16 . Compared to previously reported iron-based PB synthesized by analytically pure chemicals as cathode materials for organic SIBs, the R-PB is one of the most competitive candidates regarding both rate performance and cycling stability 18,19,20 .…”

Section: Resultsmentioning

confidence: 95%

Processing Rusty Metals into Versatile Prussian Blue for Sustainable Energy Storage

Peng

Zhang

Liu

et al. 2021

Preprint

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To reach a closed-loop material system and meet the urgent requirement of sustainable energy storage technologies, it is essential to incorporate efficient waste management into designing new energy storage materials. Here, we reported a “two birds with one stone” strategy to transform rusty iron products into Prussian blue as high-performance cathode materials and recover the rusty iron products to their original status. Owing to the high crystalline and Na+ content, the rusty iron derived Prussian blue shows a high specific capacity of 145 mAh g− 1 and excellent cycling stability over 3500 cycles. Through the in situ X-ray diffraction and in situ Raman spectra, it is found that the impressive ion storage capability and stability are greatly related to the suppressed structure distortion during the charge/discharge process. The ions migration mechanism and possibility as universal host of other kinds of ions are further illuminated by density functional theory calculations. This work provides a new strategy for recycling wasted materials into high value-added materials for sustainable battery systems, and is adaptable in the nanomedicine, catalysis, sensors, and gas storage applications.

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Prussian blue, its analogues and their derived materials for electrochemical energy storage and conversion

Cited by 219 publications

References 225 publications

Hexacyanoferrate‐Type Prussian Blue Analogs: Principles and Advances Toward High‐Performance Sodium and Potassium Ion Batteries

Hexacyanoferrate‐Type Prussian Blue Analogs: Principles and Advances Toward High‐Performance Sodium and Potassium Ion Batteries

Structure and Properties of Prussian Blue Analogues in Energy Storage and Conversion Applications

Processing Rusty Metals into Versatile Prussian Blue for Sustainable Energy Storage

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