The transformative period following 1989 ushered in significant political and economic changes across Central and Eastern Europe. Among the profound consequences of these shifts were the initiation of suburbanization processes and the uncontrolled expansion of suburbs, particularly around major cities in the region. Suburban zones experienced extensive spatial and functional alterations, while agglomeration centers, the cities themselves, underwent noteworthy transformations. The interplay of land rent dynamics contributed to the reconfiguration of functions within cities, intensifying land use. The aim of this study is to explain the spatial processes of industrial deconcentration within a post-socialist CEE city, using Wroclaw, Poland, as a case study. Employing GIS software, we examine both the spatial patterns and localization of industrial activity within the Wroclaw agglomeration. The research highlights that the peak of industrial deconcentration in the city transpired during the 1990s. Presently, the suburban zone has assumed an increasingly predominant role in the industrial activities within the agglomeration, aligning with the imperatives of sustainable development policies.