Pseudocapacitors: Enhanced Li‐Ion Accessibility in MXene Titanium Carbide by Steric Chloride Termination (Adv. Energy Mater. 9/2017)

Kajiyama, Satoshi; Szabová, Lucie; Iinuma, Hiroki; Sugahara, Akira; Gotoh, Kazuma; Sodeyama, Keitaro; Tateyama, Yoshitaka; Okubo, Masashi; Yamada, Atsuo

doi:10.1002/aenm.201770049

Cited by 5 publications

(9 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…These techniques not only shed light on the structural aspects and composition of MXenes, but also allow us to establish correlations with their properties. By exploring the structure-property relations, we aim to elucidate the mechanisms that govern MXenes' performance, enabling the design and In situ HF-formation etching [99] Alkali etching [88] Electrochemical etching [89] Organic polar solvent etching [37] Halogen etching [71] Ta 2 C Molten salt etching [32] Ti 2 C HF etching [100] In situ HF-formation etching [101] Cr 2 C Electrochemical HCl etching [102] V 2 C HF etching [103] In situ HF-formation etching [104] V 4 C 3 HF etching [105] Ta 4 C 3 HF etching [33] Mo 2 C HF etching [106] In situ HF-formation etching [107] HCl etching [39] CVD [108] Salt-templated growth [94] 𝛼-Mo 2 C CVD [109] Zr 3 C 2 HF etching [110] Hf 3 C 2 HF etching [111] ScC x Alkali etching [112] YC x HF etching [113] In situ HF-formation etching Nb 4 C 3 HF etching [114] Nb 2 C HF etching [115] Ti 3 (C 0.5 N 0.5 ) 2 Molten salt etching [32] HF etching [100] Ti 3 C 2-y O y In situ HF-formation etching [79] Ti 2 N In situ HF-formation etching [116] Molten salt etching [117] Ti 4 N 3 Molten salt etching [118] V 2 N HF etching [119] Mo 2 N Ammoniated [120] W 2 N Salt-templated growth [121] Mn 3 N 2 Salt-templated growth [93] (V 0.5 Cr 0.5 ) 3 C 2 HF etching [100] (Ti 0.5 V 0.5 ) 3 C 2 In situ HF-formation et...…”

Section: Structure-property Relations In Mxenesmentioning

confidence: 99%

Functional MXenes: Progress and Perspectives on Synthetic Strategies and Structure–Property Interplay for Next‐Generation Technologies

Meng,

Xu,

et al. 2023

Small

View full text Add to dashboard Cite

MXenes are a class of 2D materials that include layered transition metal carbides, nitrides, and carbonitrides. Since their inception in 2011, they have garnered significant attention due to their diverse compositions, unique structures, and extraordinary properties, such as high specific surface areas and excellent electrical conductivity. This versatility has opened up immense potential in various fields, catalyzing a surge in MXene research and leading to note worthy advancements. This review offers an in‐depth overview of the evolution of MXenes over the past 5 years, with an emphasis on synthetic strategies, structure‐property relationships, and technological prospects. A classification scheme for MXene structures based on entropy is presented and an updated summary of the elemental constituents of the MXene family is provided, as documented in recent literature. Delving into the microscopic structure and synthesis routes, the intricate structure‐property relationships are explored at the nano/micro level that dictate the macroscopic applications of MXenes. Through an extensive review of the latest representative works, the utilization of MXenes in energy, environmental, electronic, and biomedical fields is showcased, offering a glimpse into the current technological bottlenecks, such asstability, scalability, and device integration. Moreover, potential pathways for advancing MXenes toward next‐generation technologies are highlighted.

show abstract

Section: Structure-property Relations In Mxenesmentioning

confidence: 99%

Functional MXenes: Progress and Perspectives on Synthetic Strategies and Structure–Property Interplay for Next‐Generation Technologies

Meng,

Xu,

et al. 2023

Small

View full text Add to dashboard Cite

show abstract

“…In the first cycle of MXene, three cathodic peaks were observed near 0.42, 0.63, and 1.2 V, which could be due to initial solid electrolyte interphase (SEI) formation and the irreversible reactions. [43] The wide peaks at 0.6 and 1.1 V appear in the subsequent cycles, possibly due to the reaction of Li þ with titanium-based MXene. In addition, the well-overlapped CV curves of MXene observed after the first cycle illustrate the high reversible electrochemical reactions.…”

Section: Electrochemical Studiesmentioning

confidence: 99%

Ti₃C₂T_x–Nb₂Mo₃O₁₄ Composite as Novel Anode to Realize High Power Density Combined with High Stability in a Hybrid Lithium‐Ion Capacitor

Pawar,

Thripuranthaka,

Patrike

et al. 2023

Energy Tech

View full text Add to dashboard Cite

Lithium‐ion capacitors (LICs), with their higher energy density at high power capability, stand out as the future generation of energy‐storage devices. Herein, the nanocomposite of Ti3C2Tx MXene with Nb2Mo3O14 is prepared by a one‐step hydrothermal method and studied as an electrode material for LIC. The as‐fabricated composite MXene niobium molybdenum oxide (MXNMO) achieves a high reversible capacity of 205 mAh g−1 at 100 mA g−1 current density with outstanding cyclability. Further, asymmetric LIC full‐cell device composed of MXNMO anode with supercapacitor grade activated carbon as a cathode delivers an energy density of 37.8 Wh kg−1 (0.25 A g−1) and a higher power density of 4244 W kg−1 (5 A g−1) along with the excellent durability showing 85% capacitance retention over 4000 cycles at 0.5 A g−1.

show abstract

“…Small Methods 2023, 7, 2201609 [66,71,[74][75][76][77][78][79][80] organic electrolytes, [81][82][83][84][85][86] and ILs electrolytes. [72,[87][88][89]…”

mentioning

confidence: 99%

“…Figure 1. Summary of high-voltage MXene-based SCs working in aqueous electrolytes,[66,71,[74][75][76][77][78][79][80] organic electrolytes,[81][82][83][84][85][86] and ILs electrolytes [72,[87][88][89]. …”

mentioning

confidence: 99%

See 1 more Smart Citation

High‐Voltage MXene‐Based Supercapacitors: Present Status and Future Perspectives

Zhu

Das

et al. 2023

Small Methods

View full text Add to dashboard Cite

As an emerging class of 2D materials, MXene exhibits broad prospects in the field of supercapacitors (SCs). However, the working voltage of MXene‐based SCs is relatively limited (typically ≤ 0.6 V) due to the oxidation of MXene electrode and the decomposition of electrolyte, ultimately leading to low energy density of the device. To solve this issue, high‐voltage MXene‐based electrodes and corresponding matchable electrolytes are developed urgently to extend the voltage window of MXene‐based SCs. Herein, a comprehensive overview and systematic discussion regarding the effects of electrolytes (aqueous, organic, and ionic liquid electrolytes), asymmetric device configuration, and material modification on the operating voltage of MXene‐based SCs, is presented. A deep dive is taken into the latest advances in electrolyte design, structure regulation, and high‐voltage mechanism of MXene‐based SCs. Last, the future perspectives on high‐voltage MXene‐based SCs and their possible development directions are outlined and discussed in depth, providing new insights for the rational design and realization of advanced next‐generation MXene‐based electrodes and high‐voltage electrolytes.

show abstract

Pseudocapacitors: Enhanced Li‐Ion Accessibility in MXene Titanium Carbide by Steric Chloride Termination (Adv. Energy Mater. 9/2017)

Cited by 5 publications

References 0 publications

Functional MXenes: Progress and Perspectives on Synthetic Strategies and Structure–Property Interplay for Next‐Generation Technologies

Functional MXenes: Progress and Perspectives on Synthetic Strategies and Structure–Property Interplay for Next‐Generation Technologies

Ti₃C₂T_x–Nb₂Mo₃O₁₄ Composite as Novel Anode to Realize High Power Density Combined with High Stability in a Hybrid Lithium‐Ion Capacitor

High‐Voltage MXene‐Based Supercapacitors: Present Status and Future Perspectives

Contact Info

Product

Resources

About

Pseudocapacitors: Enhanced Li‐Ion Accessibility in MXene Titanium Carbide by Steric Chloride Termination (Adv. Energy Mater. 9/2017)

Cited by 5 publications

References 0 publications

Functional MXenes: Progress and Perspectives on Synthetic Strategies and Structure–Property Interplay for Next‐Generation Technologies

Functional MXenes: Progress and Perspectives on Synthetic Strategies and Structure–Property Interplay for Next‐Generation Technologies

Ti3C2Tx–Nb2Mo3O14 Composite as Novel Anode to Realize High Power Density Combined with High Stability in a Hybrid Lithium‐Ion Capacitor

High‐Voltage MXene‐Based Supercapacitors: Present Status and Future Perspectives

Contact Info

Product

Resources

About

Ti₃C₂T_x–Nb₂Mo₃O₁₄ Composite as Novel Anode to Realize High Power Density Combined with High Stability in a Hybrid Lithium‐Ion Capacitor