Pt(II) complexes bearing P,N-donor ligands as catalysts in chemoselective hydrosilylation, hydrogermylation, and hydroboration of terminal alkenes

Stachowiak-Dłużyńska, Hanna; Gruszczyński, Marcin; Kubicki, Maciej; Hreczycho, Grzegorz

doi:10.1016/j.jcat.2024.115494

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Cited by 4 publications

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“…Platinum-based catalysts are widely utilized and studied in this field. 65–67 The reaction of product 4e with vinylsilane resulted in the formation of product 6b with 85% yield. These reactions collectively highlight the significant application potential of the hydrosiloxanes obtained in our study.…”

Section: Resultsmentioning

confidence: 99%

Copper-driven formation of siloxanes via dehydrocoupling between hydrosilanes and silanols

Markwitz,

Łyczek,

et al. 2024

Inorg. Chem. Front.

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Section: Resultsmentioning

confidence: 99%

Copper-driven formation of siloxanes via dehydrocoupling between hydrosilanes and silanols

Markwitz,

Łyczek,

et al. 2024

Inorg. Chem. Front.

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Catalytic Construction of C(sp³)−Ge Bonds: Recent Advances and Future Perspectives

Tu,

Huang

2024

Adv Synth Catal

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Germanium (Ge), a congener of carbon, possesses unique properties that hold extensive potential for applications across multiple domains. Recent years have seen significant progress in the development of carbon‐germanium bond formation strategies, particularly those for more challenging C(sp3)‐Ge bonds. This review systematically summarizes the recent advances in C(sp3)‐Ge bond forming methodologies, with particular emphasis on (1) the versatility of transition‐metals, including iron, nickel, copper, rhodium and palladium, as catalysts in broadening reaction scope and controlling selectivity; (2) the powerfulness of organic photocatalysis in achieving mild and selective bond formation, and (3) the sustainability of catalytic electrosynthesis in facilitating chemical oxidant‐/reductant‐free conversions. Additionally, examples of (4) non‐catalytic strategies are also discussed. The representative scopes, as well as mechanistic proposals, of these protocols are highlighted. Through an overview on the current state of research, this review aims to offer insights into the catalytic construction of C(sp3)‐Ge bonds, and provide perspectives on future research directions to address the current challenges.

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Streamlining Si–O bond formation through cobalt-catalyzed dehydrocoupling

Szafoni,

Lewandowski,

Gruszczyński

et al. 2024

Chem. Commun.

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Pt(II) complexes bearing P,N-donor ligands as catalysts in chemoselective hydrosilylation, hydrogermylation, and hydroboration of terminal alkenes

Cited by 4 publications

References 80 publications

Copper-driven formation of siloxanes via dehydrocoupling between hydrosilanes and silanols

Copper-driven formation of siloxanes via dehydrocoupling between hydrosilanes and silanols

Catalytic Construction of C(sp³)−Ge Bonds: Recent Advances and Future Perspectives

Streamlining Si–O bond formation through cobalt-catalyzed dehydrocoupling

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Pt(II) complexes bearing P,N-donor ligands as catalysts in chemoselective hydrosilylation, hydrogermylation, and hydroboration of terminal alkenes

Cited by 4 publications

References 80 publications

Copper-driven formation of siloxanes via dehydrocoupling between hydrosilanes and silanols

Copper-driven formation of siloxanes via dehydrocoupling between hydrosilanes and silanols

Catalytic Construction of C(sp3)−Ge Bonds: Recent Advances and Future Perspectives

Streamlining Si–O bond formation through cobalt-catalyzed dehydrocoupling

Contact Info

Product

Resources

About

Catalytic Construction of C(sp³)−Ge Bonds: Recent Advances and Future Perspectives