Abstract. The target-like C-yield in the decay of compound systems 32 S * and 31 P * formed in 20 Ne+ 12 C and 19 F+ 12 C reactions at E * CN =60 MeV, is studied for the contribution of fusion-fission (ff) decay cross section σ f f and the deep inelastic (DI) orbiting σ orb from the compound nucleus (CN) and non-compound nucleus nCN processes, respectively. The calculations are performed using the collective clusterization of fragments within the dynamical cluster-decay model (DCM) of Gupta and collaborators. Besides studying the competition between ff and DI orbiting phenomenon in the C-yield of these systems, we exclusively investigate the preformation and barrier penetration probabilities P 0 and P as a function of angular momentum values which subsequently affects the contributions of σ f f and σ orb . For calculating the contribution of σ f f in the C-yield, we have added the contributions from all the minimized intermediate mass fragments (IMFs) for Z=6 in the calculated fragmentation potentials for 32 S * (IMFs 11,12,13 C are minimized) and for 31 P * (IMFs 12,13 C are minimized), while calculating subsequently, P 0 and the P for these IMFs. The distribution of preformed clusters/ fragments as a function of fragment mass visibly explore the nuclear structure effects for the C-yield in decay of these compound systems, wherein, it is shown to be more favoured in the decay of 31 P * in comparison to 32 S * decay. The contribution of σ orb to the C-yield is calculated from P at different allowed -values (upto max and also P≤1) of the outgoing fragments (same as that in the entrance channel, i.e., P 0 =1). Though preliminary but useful results indicates the competition between the CN and nCN process in the C-yield for the compound system 32 S * only while the decay of 31 P * is of pure CN origin, as observed in the experimental study. The calculations are in good comparison with the available experimental data.