The concrete with different fibre and ratio can lead to different performance. This paper studies the mechanical properties of concrete by changing the ratio of PVA fibre and steel fibre. Three kinds of ratio of the PVA fibre and steel fibre are studied. They are 0% PVA fibre and 0% steel fibre, 0.25% PVA fibre and 0.75% steel fibre, 0.5% PVA fibre and 0.5% steel fibre. The compressive strength, flexural strength, bending toughness are tested. The test result shows that the compressive strength of the P0.25S0.75 increases. While the group of P0.5S0.5 shows a little range of decreasing. The 28d flexural strength of P0.25S0.75 and P0.5S0.5 increases 2.3 and 30.2% respectively. The loading-deflection curves of P0.25S0.75 and P0.5S0.5 all appear strain harden property. By the mixing amount of the PVA fibre increasing, the cracking strength and limitation bearing ability can all be enhanced. The areas under the curve enlarge and the toughness of the concrete are enhanced. The bending toughness of P0.5S0.5 is much better than the P0.25S0.75 but the difference is not very large.