“…Evidence suggests that single-crystal (i.e., well ordered) graphite targets produce larger clusters than do amorphous carbon targets. 49,58 With laser irradiation in the visible and IR, small clusters consisting of a few carbon atoms are produced, 44,55,56,[59][60][61][62][63][64][65][66][67][68][69][70][71][72] but larger clusters (with as many as 100 carbon atoms) are also commonly observed in these wavelength regions under vacuum. 46,56,61,62,73 At these wavelengths large clusters, fullerenes, and nanoparticles can be formed at higher pressures 53,54,64,[74][75][76][77][78] or when expanded in a buffer gas into a vacuum.…”