By adiabatic difference-frequency generation in an aperiodically poled nonlinear crystal-a nonlinear optical analog of rapid adiabatic passage in a two-level atomic system-we demonstrate the conversion of a 110 nm band from an octave-spanning Ti:sapphire oscillator to the infrared, spanning 1550 to 2450 nm, with near-100% internal conversion efficiency. The experiment proves the principle of complete Landau-Zener adiabatic transfer in nonlinear optical wave mixing. Our implementation is a practical approach to the seeding of high-energy ultrabroadband optical parametric chirped pulse amplifiers. © 2012 Optical Society of America OCIS codes: 320.7110, 190.4975, 020.2649. Today's demand for octave-spanning bandwidth sources of coherent optical pulses-at wavelengths other than the Ti:sapphire (Ti:S) oscillator's 800 nm centered band -is widened by the need for seed pulses for ultrabroadband optical parametric amplifiers (OPAs). Such systems today include wavelength multiplexing schemes that coherently synthesize few-cycle OPA pulses of several colors to generate high-energy subcycle waveforms [1], and these require a multiple-octave-spanning seed spectrum. Ti:S oscillator pulses, extended to other spectral ranges by sum-or difference-frequency generation (SFG, DFG), are often used. For example, in [1-4], 2 μm optical parametric chirped pulse amplifier (OPCPA) systems amplify a broadband Ti:S pulse converted to the mid-IR via intrapulse DFG. This method has poor efficiency, which is a result of the tight focusing and transform-limited duration needed to reach an intensity high enough for nonlinear interaction, resulting in a short interaction length. The seed energy in these systems is only a few pJ, less than 1% of the Ti:S power. This has practical consequences since the low seed energy in these high-gain amplifiers is the root of severe superfluorescence noise contamination, effectively limiting the overall amplifier gain [5].In this letter, we report near-100% conversion of a broadband Ti:S oscillator band to the mid-IR using the adiabatic DFG technique [6], thus proving the principle of complete Landau-Zener (LZ) adiabatic transfer in nonlinear optical wave mixing. The complete conversion succeeds for the full temporal and spatial extents of the Ti:S beam. Moreover, it covers a 0.7 octave idler band and is potentially scalable to multiple octaves from a single nonlinear crystal. Here we discuss an implementation ideally suited for the seeding of OPCPAs, but the method could be useful generally for providing nJ energy broadband infrared pulses with up to an MHz repetition rate.Adiabatic frequency conversion applies the principle of rapid adiabatic passage (RAP) for full transfer of population between states of a 2-level atom to optical frequency conversion, a concept explored in several previous works [6][7][8][9]. Notably, in the mixing of frequencies, ω 3 ω 1 − ω 2 , where ω 1 > ω 2 , ω 3 , through a quadratic electric susceptibility, the equations of motion are isomorphic to the driven optical Bloch equat...