Spin dependent selection rules for photonic transitions in hydrogen-like atoms is derived by using the solution of Dirac equation for hydrogen-like atoms. It is shown that photonic transitions occur when [ Δj=0,±1,±2, while Δm<sub>j</sub>=0,±1,±2 ]. By applying the spin dependent selection rules, we can explain the observed (6s→7s) transition in Cesium (Cs) atom