Pure rotational Coherent anti‐Stokes Raman spectroscopy of water vapor and its relevance for combustion diagnostics

Abstract

In this work, we report for the first time the rotational coherent anti‐Stokes Raman spectroscopy (CARS) spectrum of water vapor, recorded through experiments at 400 K and 670 K for Raman shifts up to 600 cm−1. Using the standard dual‐broadband pure rotational CARS approach, the resonant structure was overwhelmed by a strong non‐resonant background. By employing a polarization technique, this background could be suppressed and the resonant structure discerned. The spectral line structure matched spectra from spontaneous rotational Raman scattering found in the literature. The CARS signal intensity at the highest peak from water vapor at 400 K was more than five orders of magnitude weaker than for N2 because of a low Raman cross section and a larger number of transitions. Due to the weak resonant signal, water vapor is an unsuitable candidate for CARS thermometry and relative concentration measurements in combustion. Still, rotational CARS spectra from product gases in combustion will be affected by the presence of water, which is briefly discussed. Copyright © 2013 John Wiley & Sons, Ltd.

Advances in nonlinear optical spectroscopies: a historical perspective of developments and applications presented at ECONOS

“…Other groups extended CARS to new molecules and new pieces of information that can be gained. Bengtsson et al implemented strategies for utilizing the rotational CARS signals of nitrous oxide and water vapor . Although both species are not desirable target species, for example, for thermometry, their signals may interfere with that of nitrogen or oxygen.…”

Oxygen rotational Raman linewidth determination considering nonmonoexponential decoherence behavior

“…[17,22] Oxygen is abundant in the typically lean oxy-fuel combustion environment and exhibits a large Raman cross-section compared with H 2 O for instance. [5,19,23,24] However, the knowledge about empirical parameters based on S-branch Raman linewidth of oxygen is small. [21,25] Up to now the S-branch evaluation is based on Q-branch linewidth data, which can deviate from the S-branch data.…”

Recent advances in linear and nonlinear Raman spectroscopy. Part VIII

“…Their measurements were carried out at 400 K and 670 K for Raman shifts up to 600 cm −1 . They found that due to the weak resonant signal, water vapor is an unsuitable candidate for CARS thermometry and relative concentration measurements in combustion . Rocha‐Mendoza et al .…”