We investigate the isoscalar and isovector E1 response of neutron-rich nuclei, within a semiclassical transport model employing effective interactions for the nuclear mean-field. In particular, we adopt the recently introduced SAMi-J Skyrme interactions, whose parameters are specifically tuned to improve the description of spin-isospin properties of nuclei. Our analysis evidences a relevant degree of isoscalar/isovector mixing of the collective excitations developing in neutron-rich systems. Focusing on the low-lying strength emerging in the isovector response, we show that this energy region essentially corresponds to the excitation of isoscalar-like modes, which also contribute to the isovector response owing to their mixed character. Considering effective interactions which mostly differ in the isovector channels, we observe that these mixing effects increase with the slope L of the symmetry energy at saturation density, leading to a larger strength in the low-energy region of the isovector response. This result appears connected to the increase, with L, of the neutron/proton asymmetry at the surface of the considered nuclei, i.e., to the extension of the neutron skin.