Pyridine-based macrocycles containing N, O, and S and their use as ion-selective electrodes. Crystal structures of 15-aza-6-oxa-3,9-dithiabicyclo[9.3.1]pentadeca-1(15),11,13-triene and (15-aza-6-oxa-3,9-dithiabicyclo[9.3.1]pentadeca-1(15),11,13-triene)dichlorocopper(II)

Highly Selective and Sensitive Membrane Sensors for Copper(II) Ion Based on a New Benzo‐Substituted Macrocyclic Diamide 6,7,8,9,10‐Hexahydro‐2H‐1,13,4,7,10‐benzodioxatriazacyclopentadecine‐3,11(4H,12H)‐dione

“…These copper ion carriers include a thiaglutaric diamide derivative [10], small size thia crown ethers [11,12], pyridine- [13] and phenanthroline-based aza-thio crowns [14], calix [4]arens [15] Schiffs bases [16 -19], chelating ionophores [20,21], thiophosphoril-containing macrocycles [22] and macrocyclic diamides [23]. However most of these Cu(II)-selective membrane suffer interfering effects from Co 2þ , Ni 2þ , Cd 2þ , Hg 2þ and Ag þ ions as well as limited linear ranges.…”

Can Serendipity Still Hold Any Surprises in the Coordination Chemistry of Mixed-Donor Macrocyclic ligands? The Case Study of Pyridine-Containing 12-Membered Macrocycles and Platinum Group Metal ions PdII, PtII, and RhIII

“…In fact, in the case of L 1 , only the X-ray crystal structure of the neutral complex [Cu( L 1 )Cl 2 ] is known [ 34 ], while for L 3 , only the 1:1 complex cations [Cu( L 3 )] 2+ and [Zn( L 3 )] 2+ have been reported as nitrate salts [ 13 ]. In the case of L 2 , the polymeric complexes [Ag( L 2 )] n (CF 3 CO 2 ) n ·nH 2 O [ 35 ] and [Ag( L 2 )] n (NO 3 ) n [ 36 ] were structurally characterized along with the discrete 1:1 complex cations [Cu( L 2 )] 2+ [ 35 ] and [Hg( L 2 )Cl] + [ 37 ] (NO 3 − and HgCl 3 − counter-anions, respectively), and the binuclear compound [Ni 2 ( L 2 ) 2 Cl 2 ](BF 4 ) 2 ·1.5MeNO 2 [ 22 ].…”

“…In those cases, the nature of the donor atom sets, the conformational constraints determined by the phen unit on the thioether linkers of the two pentadentate rings, and the locked [4+1] coordination sphere imposed on the Pd II and Pt II ions in their 1:1 complexes were responsible for the stabilization of the corresponding low-valent complexes of Pd I and Pt I [ 32 , 33 ]. The crystal structures of L 1 and L 2 are known [ 34 , 39 ]. In both structures, the aliphatic chain of the rings is tilted over the plane containing the pyridine unit—presumably because of the repulsion between the two sulfur atoms close to the aromatic ring [ 34 ].…”

Template Synthesis and Characterization of Host (Nanocavity of Zeolite Y)-Guest ([Cu([18]aneN4S2)]2+, [Cu([20]aneN4S2)]2+, [Cu(Bzo2[18]aneN4S2)]2+, [Cu(Bzo2[20]aneN4S2)]2+) Nanocomposite Materials

“…3 Synthesis and characterization of most transition metal complexes with macrocyclic mixed donor ligands containing mixed donors of nitrogen, oxygen and sulfur has been studied. [4][5][6][7][8][9][10][11][12][13][14][15][16] However, most of them were polyaza macrocyclic ligands, and macrocyclic mixed donor ligands containing N-S in the nanopores of zeolite Y have not been to some extent reported to date. The term nanopore materials have been used for those porous materials with pore diameters of less than 100 nm.…”