Pyridoxal phosphate-dependent reactions in water pools

The oxidation of iodide by persulphate has been studied in different sodium bis-2-ethylhexylsulphosuccinate (aerosol-OT or AOT)-oil-water microemulsions at 298 K. The rate of this reaction is appreciably higher in a microemulsion than when it takes place in a conventional aqueous medium. The dependence of the rate constant on the surfactant concentration as well as on the molar ratiohas been examined. The results are interpreted on the basis of the anionic nature of the reactants and the surfactant itself, and the high concentrations of sodium cations inside the aqueous cores. The dependence of the rate constant on the nature of the organic phase present in the system has also been investigated.

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Microemulsions: An Overview

Paul¹,

Moulik²

1997

Journal of Dispersion Science and Technology

293

160

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Pyridoxal phosphate-dependent reactions in water pools

Cited by 3 publications

References 22 publications

Microemulsions as a medium in chemical kinetics, II. The I⁻ + S₂O₈⁼ and crystal Violet + OH⁻ reactions in different surfactant/oil/water microemulsions

Microemulsions as a medium in chemical kinetics, II. The I⁻ + S₂O₈⁼ and crystal Violet + OH⁻ reactions in different surfactant/oil/water microemulsions

Kinetics of the oxidation of iodide by persulphate in AOT–oil–water microemulsions

Microemulsions: An Overview

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Pyridoxal phosphate-dependent reactions in water pools

Cited by 3 publications

References 22 publications

Microemulsions as a medium in chemical kinetics, II. The I− + S2O8= and crystal Violet + OH− reactions in different surfactant/oil/water microemulsions

Microemulsions as a medium in chemical kinetics, II. The I− + S2O8= and crystal Violet + OH− reactions in different surfactant/oil/water microemulsions

Kinetics of the oxidation of iodide by persulphate in AOT–oil–water microemulsions

Microemulsions: An Overview

Contact Info

Product

Resources

About

Microemulsions as a medium in chemical kinetics, II. The I⁻ + S₂O₈⁼ and crystal Violet + OH⁻ reactions in different surfactant/oil/water microemulsions

Microemulsions as a medium in chemical kinetics, II. The I⁻ + S₂O₈⁼ and crystal Violet + OH⁻ reactions in different surfactant/oil/water microemulsions