Thermal-electric conversion is crucial for smart energy control and harvesting, such as thermal sensing and waste heat recovering. So far, people are aware of only two ways of direct thermal-electric conversion, Seebeck and pyroelectric effects, each with distinct working conditions and limitations. Here, we report the third way of thermal-electric conversion beyond Seebeck and pyroelectric effects. In contrast to Seebeck effect that requires spatial temperature difference, the-third-way converts the time-dependent ambient temperature fluctuation into electricity, similar to the behavior of pyroelectricity. However, the-third-way is also distinct from pyroelectric effect in the sense that it does not require polar materials but applies to general conducting systems. We demonstrate that the-third-way results from the temperature-fluctuation-induced dynamical charge redistribution. It is a consequence of the fundamental nonequilibrium thermodynamics and has a deep connection to the topological phase in quantum mechanics. The findings expand our knowledge and provide new means of thermal-electric energy harvesting.About 90 percent of the world's energy is utilized through heating and cooling, which makes energy waste a great bottleneck to the sustainability of any modern economy [1]. In addition to developing new technology of smart heat control [2], the global energy crisis can be alleviated by recovering the wasted thermal energy. In view of the inconvenient truth that more than 60% of the energy utilization was lost mostly as wasted heat [3], harvesting the thermal energy becomes critical to provide a cleaner and sustainable future [1].Thermal-electric energy harvesting mainly relies on two principles: Seebeck effect (Fig. 1A) and pyroelectric effect (Fig. 1B). The Seebeck effect utilizes the spatial temperature difference between two sides of materials to drive the diffusion of charge carriers so as to convert heat into electricity [4,5]. Besides recovering waste heat, Seebeck effect with its reciprocal has wide applications of cooling, heating, power generating [6] and thus has revitalized an upsurge of research interest recently [7,8]. However, when the ambient temperature is spatially uniform, we have to resort to the pyroelectric effect [9], which utilizes the time-dependent temperature variation to convert heat into electricity but is restricted to pyroelectric materials [10]. This is due to the fact that the temporal temperature fluctuation modifies the spontaneous polarization of polar crystals, which consequently redistributes surface charges and produces temporary electric current [11,12]. In addition to thermal-electric energy harvesting [13][14][15][16][17], pyroelectric effect has widespread applications in long-wavelength infrared sensing, motion detector, thermal image [11], and even nanoscale printing [18].However, since Seebeck and pyroelectric effects have been known for quite a long time, one cannot help wondering: Does Nature only offer us these two means for thermal-electric energy harvestin...