The measurements of X-ray absorption spectra (XAS) and Xray absorption fine structure (XAFS) have usually been performed by using a synchrotron radiation facility. It is widely believed that high intensity and monochromatized X-rays are necessary for XAS and XAFS experiments. In the present paper, however, we report K-edge XAS measurements of Ca contained in paper sheets using a dry electric battery XAS spectrometer.As one of the smaller X-ray sources, X-ray emission using the charging phenomenon of an insulator has been reported by several authors. [1][2][3][4] Recently, a novel and portable X-ray emitter using the charging phenomena of a pyroelectric crystal has become commercially available; its size is 15 mm in diameter and 10 mm in height. With a controller box that works off a 9 V dry electric battery, the full dimensions of this device are only 125 mm in length, 45 mm in width and 30 mm in height. Kawai et al. 5 reported X-ray fluorescence (XRF) analysis of metal oxides using this X-ray emitter. Ida et al. reported the XRF analysis of the small amount of Fe in aluminum foil 6 as well as the Cr analysis in steel. 7 They also performed XRF analysis of leathers, 8 glass and ceramics, 9 demonstrating the capability of this X-ray emitter as a source for a portable XRF instrument.The X-ray emitter used in the present measurement was a COOL-X (Amptek, Bedford, MA, USA), where LiTaO3 and Cu were used as the pyroelectric crystal and the target metal, respectively. Collision of electrons with the pyroelectric crystal as well as the metal target generated X-rays, which consisted of Cu K and Ta L lines and Bremsstrahlung radiation.Transmission X-rays were detected by a portable Si PIN detector XR-100CR (Amptek), of which the dimensions were the same as those of the COOL-X. One or two pieces of alkaline paper (name cards) with the thickness of 200 µm, which contained 2 mg/cm 2 (13 wt%) CaCO3 as filler and pigment, were measured. The geometry of the experiment is shown in Fig. 1. The distance between the X-ray emitter and the detector was 150 mm. The duration time for one spectrum was 400 s. In order to deliberately lower the detection of fluorescent X-rays from the sample, the sheet was placed close to the X-ray generator at a distance of 25 mm. The same sample was measured with two geometries: one for normal incidence (θ = 90˚) and the other the grazing incidence (θ = 30˚). Figure 2 shows the raw transmission spectra for no, one and two pieces of paper in the normal incident geometry. The spectrum for without paper was I0, where the main peaks were X-ray absorption spectral (XAS) analysis is performed with a combination of a 9 V dry electric battery X-ray generator and a portable Si PIN X-ray detector. The calcium K edge (4.0 keV) in paper is measured with a grazing incidence geometry, which suppressed the artifact due to the Kα X-ray fluorescence peak at 3.5 keV. The 9 V dry battery X-ray emitter is useful for portable XAS measurements. Fig. 2 Raw X-ray transmission spectra (I) of one and two pieces of paper wer...