The aim of this study is to establish the thermal characteristics of a biocomposite (Arbofill kokos®), stabilized with different natural phenolic additives, in order to check the antioxidant capacity of the resulting compounds on the biocomposite. The phenolic compounds used were thymol, carvacrol, α-tocopherol and tannic acid, and the concentrations used were 0.5wt% and 2wt% of each compound. The results obtained were compared with the same biocomposite stabilized with an industrial antioxidant agent (octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate). Thermo-analytical techniques were used (DSC and TGA) to carry out the study. The antimicrobial effect of these natural phenolic compounds on the biocomposite was also studied by analyzing of the growth of bacterial colonies. The comparison between the phenolic compounds and the industrial compound showed good antioxidant action of the phenolic compounds on the base biocomposite; in all the mixtures of biocomposite and antioxidant agent the oxidation onset temperature (OOT) of the biocomposite increased. Of all the phenolic compounds studied the highest OOT was achieved with α-tocopherol, which, compared with the temperature of the base composite, showed an increase of almost 45%.