2002
DOI: 10.1021/ie010726j
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Qualitative Analysis for Homogeneous Azeotropic Distillation. 2. Bifurcation Analysis

Abstract: Studying global mass balances and how they interact with the shape of column profiles, Morari, M. Ind. Eng. Chem. Res. 2002, 41, XXXX) developed a graphical method for a qualitative stability analysis of steady-state profiles in homogeneous azeotropic distillation columns. Based on the qualitative stability analysis, here it is shown how bifurcation diagrams can be constructed containing information on the stability of the equilibria. Fold, Hopf, and homoclinic bifurcations as well as more complex bifurcatio… Show more

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Cited by 15 publications
(15 citation statements)
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“…Hernjak et al12 proposed a qualitative process operability analysis method based on three main process characteristics: the degree of nonlinearity, process dynamics and degree of interaction between loops. Research effort has also concentrated on the nonlinear phenomena that is known to generate operability difficulties such as multiple equilibrium points, limit cycles, chaotic behavior and bifurcations, e.g.,13–17 However, none of the above open‐loop methods addresses the plant‐wide operability analysis problem from a network perspective.…”
Section: Introductionmentioning
confidence: 99%
“…Hernjak et al12 proposed a qualitative process operability analysis method based on three main process characteristics: the degree of nonlinearity, process dynamics and degree of interaction between loops. Research effort has also concentrated on the nonlinear phenomena that is known to generate operability difficulties such as multiple equilibrium points, limit cycles, chaotic behavior and bifurcations, e.g.,13–17 However, none of the above open‐loop methods addresses the plant‐wide operability analysis problem from a network perspective.…”
Section: Introductionmentioning
confidence: 99%
“…The applications of bifurcation analysis as a powerful nonlinear system analysis tool for chemical processes have been widely reported. [215][216][217][218][219][220][221][222][223][224][225] Morari suggested that bifurcation analysis should be used in controllability analysis for nonlinear systems. 226 Input/output multiplicity is a complex phenomenon that can be encountered in chemical processes and will adversely affect the performance of the closed-loop system, subject to the changing operating conditions.…”
Section: Bifurcation Analysis-based Methods For Process Designmentioning
confidence: 99%
“…Applications are available in the chemical engineering literature. [36][37][38][39] Interval methodology is also applied (see, for example, Tolsma and Barton, 40 Gehrke and Marquardt, 41 or Gwaltney et al 42 ).…”
Section: Search For Bifurcation Points With Interval Methodologymentioning
confidence: 99%