Sum frequency vibrational spectroscopy (SFVS) spectra indicate that a very ordered water structure exists in the stablewater film at a hydrophilic silica surface during contact with a bubble and that the extent of hydrogen bonding increases with an increase in contact pressure. In contrast, the SFVS spectra of water at a hydrophobic silica surface show a lack of hydrogen bonding and are characterized by a distinct absorption at about 3700 cm −1 , similar to the spectrum of the air/water interface. These results suggest the presence of a water exclusion zone at the hydrophobic surface, as supported by X-ray reflectivity measurements reported in the literature, by AFM images, and by results from molecular dynamics simulations. Of course, the water film at the hydrophobic surface is unstable with film thinning and rupture upon bubble contact. Under these circumstances, it is shown that an attractive van der Waals force between a bubble and the hydrophobic surface can be expected when the water exclusion zone is taken into consideration. As the thickness of the water exclusion zone increases to a thickness corresponding to the size of nanobubbles, the calculated attractive van der Waals force increases. This analysis may help to explain the so-called 'short-range' and 'long-range' hydrophobic forces.
IntroductionThe interaction of bubbles with solid and liquid particles in aqueous systems is a fundamental phenomenon of interest in many areas of technology. These interactions are important in the development of improved flotation technologies for the recovery of valuable minerals, for water treatment, for wastepaper recycle, and so on. Flotation is accomplished by the attachment of air bubbles at the surface of hydrophobic particles and their separation from suspension, as practiced in the processing of mineral and energy resources. Attention has been given to the physics of bubble interactions at surfaces, including the bubble approach to the surface, the formation of the intervening water film, the kinetics of film thinning, the critical film thickness, the film's stability, the interaction forces and the disjoining pressure.1-10 All these studies indicate that the structures of these water films differ from those of water in the bulk phase.It has been established for silica surfaces that water films between a negatively charged bubble and the negatively charged silica surface are on the order of 100 nm in thickness. The films are stable at clean hydrophilic silica surfaces and metastable at methylated hydrophobic silica surfaces.1 These pioneering studies have