Quantifying the pollution characteristics of chemical components in PM2.5 in the North China Plain, China: Spatiotemporal variation and health risk

Ke, Yue; Wang, Honglei; Wu, Zihao; Liu, Sihan; Zhao, Tianliang; Yin, Yan

doi:10.1016/j.atmosenv.2023.119860

Cited by 12 publications

(1 citation statement)

References 55 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Carbonaceous aerosols significantly contribute to PM 2.5 (particulate matter with an aerodynamic diameter ≤ 2.5 µm), accounting for approximately 10-70% of its mass concentration (Kanakidou et al, 2005;Hu et al, 2012;Tiwari et al, 2016;Ke et al, 2023). Their presence in the atmosphere has profound implications for air quality, climate, and human health, rendering them a subject of global concern (Chung, 2002;Pöschl, 2005;Highwood and Kinnersley, 2006;Cao et al, 2012;Liu et al, 2023).…”

Section: Introductionmentioning

confidence: 99%

Measurement Report: Long-term Assessment of Primary and Secondary Organic Aerosols in Shanghai Megacity throughout China’s Clean Air Actions since 2010

Yu,

Chang,

Cheng

et al. 2024

Preprint

View full text Add to dashboard Cite

Abstract. A growing body of research has demonstrated the effectiveness of China’s Air Pollution Prevention and Control Action Plan in controlling PM2.5 pollution. However, there is a lack of long-term studies investigating the impact of these abatement policies on carbonaceous aerosols in PM2.5, particularly secondary organic carbon (SOC). Shanghai, as China’s largest megacity and prominent industrial hub, serves as a crucial gateway to the nation’s rapid development with a population exceeding twenty million. In this study, we conducted hourly online measurements of organic carbon (OC) and elemental carbon (EC) in PM2.5 in Shanghai from July 2010 to July 2017. The results revealed that the annual concentrations (mean ± 1 σ) of OC and EC reached their peaks in 2013 (9.5 ± 6.4 and 2.7 ± 2.6 µg m-3 to 3.0 ± 2.3 µg m-3 and 2.7 ± 2.1 µg m-3). Subsequently, a consistent year-by-year decrease in both OC and EC concentrations was observed, mirroring the trend observed for PM2.5. Primary organic carbon (POC), the primary component of OC, accounted for an average of 65.6 %, displaying similar trends to OC. This finding indicates the effectiveness of primary emission control measures. However, the concentration of secondary organic carbon (SOC) did not decrease from 2013 to 2017, remaining relatively stable within the range of 2.7 ± 2.6 µg m-3 to 3.0 ± 2.3 µg m-3. When considering data from previous studies in Shanghai, concentrations of SOC did not exhibit a noticeable decline until 2018, coinciding with the implementation of measures targeting volatile organic compounds (VOCs) emissions. Seasonally, with the exception of 2011, OC and EC concentrations were highest during winter, likely influenced by unfavourable meteorological conditions and long-range transport. SOC displayed no distinct seasonal fluctuations, as its formation is influenced by both photochemical reactions and meteorological conditions. POC and SOC exhibited different diurnal patterns, but neither showed a significant weekend effect, suggesting limited reduction in anthropogenic activities during weekends. Furthermore, SOC concentrations exhibited simultaneous increases in summer, particularly when O3 concentrations exceeded 50 µg m-3, indicating that stronger oxidation reactions contribute to higher SOC concentrations. Our findings also revealed concentration gradients of SOC dependent on wind direction (WD) and wind speed (WS), with higher concentrations typically observed for winds originating from the southwest and northwest. Potential sources from distant regions were analyzed using the potential source contribution function (PSCF), indicating that the geographical potential source area is concentrated near the middle and lower Yangtze River.

show abstract