A log Calabi-Yau surface (X, D) is given by a smooth projective surface X, together with an anti-canonical cycle of rational curves D ⊂ X. The homogeneous coordinate ring of the mirror to such a surface -or to the complement X \ D -is constructed using wall structures and is generated by theta functions [6,7]. In [1], we provide a recipe to concretely compute these theta functions from a combinatorially constructed wall structure in R 2 , called the heart of the canonical wall structure. In this paper, we first apply this recipe to obtain the mirror to the quartic del Pezzo surface, denoted by dP 4 , together with an anti-canonical cycle of 4 rational curves. We afterwards describe the deformation quantization of this coordinate ring, following [4]. This gives a non-commutative algebra, generated by quantum theta functions. There is a totally different approach to construct deformation quantizations using the realization of the mirror as the monodromy manifold of the Painlevé IV equation [5,8]. We show that these two approaches agree.