Solid-state electrolyte
sensors operate at high temperatures for
extended periods of time, which can cause internal structural deformation
and degradation of material properties due to issues such as mismatched
coefficients of thermal expansion. Therefore, predicting and extending
the lifetime of sensors are urgent and important issue. In this study,
the relationship between the damping coefficient of electrode materials
and the porosity and temperature was determined using atomic anharmonic
theory. A lifetime model for the porous platinum electrode was established,
and the effects of porosity and anharmonic atomic vibrations on the
characteristic lifetime and reliability of porous platinum electrodes
were investigated. The results show that the morphology parameters
of the electrode material increase nonlinearly with increasing temperature
but the change is very small. The characteristic lifetime decreases
sharply at first and then tends to remain constant with increasing
porosity. In the case of the simple harmonic approximation, neither
the characteristic lifetime nor the reliability of the electrode material
changes with temperature. However, considering the anharmonic atomic
vibration, the characteristic lifetime and reliability of the electrode
material are smaller than those of the simple harmonic approximation,
and both of them decrease with increasing temperature. The higher
the temperature, the greater the difference between the results of
anharmonic and harmonic, and the more significant the anharmonic effect.
The reliability decreases with an increasing porosity and time.