Quantitative Evaluation of the Effects of Salt Concentration and pH on the Self-Assembly of Kaolin Nanoplatelets

Abstract

Diffusion of pollutants in the earth's strata threatens both the environment and human health. The clay soil microstructure that plays a crucial role in the diffusion of pollutants is significantly influenced by the pore water chemistry. However, there is still a lack of quantitative evaluation of pore water chemistry on clay fabric evolution. To bring new insights, we systematically examined the impact of water chemistry (mainly refers to salt ion concentration and pH) on the self-assembly form (fabric) of kaolin platelets and evaluated the fabric quantitatively. The results show that as the salt ion concentration increases, the "kaolin book" structure is formed, which can be captured by the ( 001) and (020) pole figures. Under acidic conditions, kaolin platelets turn randomly arranged; however, with the increase of pH, the edge-to-face (EF) microstructure of kaolin platelets gradually changes to a face-to-face (FF) structure. Under alkali-eq conditions, kaolin platelets form a dispersion assembly dominated by FF repulsion. However, the strong alkaline condition triggers the decomposition of kaolin, leading to a notable decrease in the maximum pole density. The conclusions were substantiated through insightful AFM tests. Moreover, we addressed the advantages and limitations of 1DXRD and 2DXRD by analyzing the trend between the OI and pole density, with 2DXRD being favored for its accuracy. Overall, this study provides insights into clay platelets and the self-assembly of kaolin under different water chemistry conditions, which have significant implications for predicting and modeling the physical properties of clay under special environmental conditions.

Sustainable Coating Materials: Exploring the Influence of Adjuvants on Kaolinite Suspension with Insights from Five Local Mining Clays

“…Moreover, the sedimentation behavior of kaolinite platelets exhibited notable variations in response to fluctuations in environmental salt ion and pH. The microstructure study findings revealed differences in the compactness of clay orientation, with a distinct order observed in salt (kaolin book), alkaline (face-to-face repulsion), water, and acidic condition (randomly face-to-face). , …”

“…The microstructure study findings revealed differences in the compactness of clay orientation, with a distinct order observed in salt (kaolin book), alkaline (face-to-face repulsion), water, and acidic condition (randomly face-to-face). 26 , 27 …”