Quantitative Investigation of the Morphologically Corrugated CVD-Grown Graphene Monolayer Surface with a Nanoparticle-on-Mirror System

Abstract

Graphene can be used as a starting material for the synthesis of useful nano-complexes for exible, transparent electrodes, therapeutic, bio-diagnostics and bio-sensing. In order to apply graphene in the medical eld, chemical vapor deposition (CVD) method has been mainly utilized considering its large and near-homogenious carbon constituents. Especially, the less degree of perturbation of graphene monolayer (GM), which is followed by the underneath catalytic Cu surface morphology, is very crucial in terms of providing the suspended GM and relatively uent lateral carrier mobility with lower sheet resistance value. In this work, we can suggest a surface-Enhanced Raman Spectroscopic (SERS) indicator in a quantitative way on the status of z-directional morphological corrugation of a CVD-grown GM (CVD-GM) by applying a Nanoparticle-on-Mirror (NPoM) system composed of Au nanoparticle (NP) / CVD-GM / Au thin lm (TF) plasmonic junction structure. A new (or enhanced) Radial Breathing Like Mode (RBLM) SERS signal around ~150 cm -1 from CVD-GM spaced in NPoM is clearly observed by employing a local z-polarized incident eld formed at the Au NP-Au TF plasmonic gap junctions.With this observation, the value of I[out-of-plane, RBLM] / I[in-plane, [2D] at certain domains, it can be suggested as a new optical nano-metrology value to relatively determine between lower z-directional morphological corrugation (or protrusion) status of a CVD-GM spaced in our NPoM system (lower I[RBLM] / I[2D] value) and higher degree of lateral carrier mobility of the CVD-GM associated with lower sheet resistance values as a result of higher blue-shifted Raman in-plane (G, 2D) peak maximum position.Furthermore, we will also expect the bio-sensing performances by utilizing the high speci c surface area and ultrahigh exibility of the CVD-GM in one of the future prospective works such as pressure-strain, strain-to-electricity and chemical-coupled sensor via I[RBLM] / I[2D] values.