Quantum-Chemical Model of the Structure of Iron Silicate Polysulfide

Baraeva, Linara; Yusupova, Alsu; Ахметова, Р. Т.; Хацринов, А. И.; Межевич, Ж В

doi:10.1134/s0036024419060049

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Nucleophilic and Electrophilic Activation Of The S 8 Ring In1

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2021

2023

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“…For example, it is possible to open the S 8 ring in the presence of silica gel, which binds the electrophilic centres of Lewis acids (Scheme 15). The effectiveness of zinc chloride, 146,147 titanium(IV) chloride, [148][149][150] iron(III) chloride, 151 and aluminium chloride 152,153 in the presence of silica gel has been demonstrated, which widens the options for regulating the properties of their corresponding sorbents.…”

Section: Nucleophilic and Electrophilic Activation Of The S 8 Ring Inmentioning

confidence: 99%

Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects

et al. 2021

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Section: Nucleophilic and Electrophilic Activation Of The S 8 Ring Inmentioning

confidence: 99%

Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects

et al. 2021

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Nucleophilic activation of the sulfur S8 cyclic form as a green chemistry tool

Tarasova

Krivoborodov²,

Mezhuev³

2023

Russ Chem Bull

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Current Trends in the Synthesis of Inorganic and Organoelement Phosphorus- and Sulfur-Containing Polymers. A Review

Tarasova,

Krivoborodov,

Mezhuev

2023

Dokl Chem

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An analysis of literature data on the set of reactions for the production of macromolecules with a high content of phosphorus and sulfur has been carried out, and basic approaches that allow the introduction of these elements into the composition of polymers and polymeric materials have been considered in compliance with the fundamental principles of green chemistry. Methods for synthesis of functional polymers under mild conditions that require minimal energy input from external sources, which can become new growth points for green industrial technologies, are considered. Particular attention focuses on the synthesis of polyphosphazenes and polyphosphoesters for biomedical purposes, as well as on the inverse vulcanization reaction to give polymers used in sorption wastewater treatment, the creation of current sources, and IR optics.

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Quantum-Chemical Model of the Structure of Iron Silicate Polysulfide

Cited by 4 publications

References 0 publications

Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects

Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects

Nucleophilic activation of the sulfur S8 cyclic form as a green chemistry tool

Current Trends in the Synthesis of Inorganic and Organoelement Phosphorus- and Sulfur-Containing Polymers. A Review

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