Along the line of singular value estimates for commutators by Rochberg-Semmes, Lord-McDonald-Sukochev-Zanin and Fan-Lacey-Li, we establish the endpoint weak Schatten class estimate for commutators of Riesz transforms with multiplication operator M f on Heisenberg groups via homogeneous Sobolev norm of the symbol f . The new tool we exploit is the construction of a singular trace formula on Heisenberg groups, which, together with the use of double operator integrals, allows us to bypass the use of Fourier analysis and provides a solid foundation to investigate the singular values estimates for similar commutators in general stratified Lie groups. 45] further studied the Schatten-Lorentz class L p,q estimates for [R ℓ , M f ] and investigated the endpoint estimate for [R ℓ , M f ] ∈ L n,∞ . In a paper which links these commutators to noncommutative geometry, Connes-Sullivan-Teleman [16] further announced the full characterisation of the endpoint for [R ℓ , M f ] ∈ L n,∞ via a homogeneous Sobolev space Ẇ1,n (R n ). Recently, Lord-McDonald-Sukochev-Zanin [32] provided a new proof for Connes-Sullivan-Teleman [16] by proving that quantised derivatives d¯f of Alain Connes (introduced in [15, IV] on R n , n > 1) is in L n,∞ if and only if f is in the homogeneous Sobolev space Ẇ1,n (R n ), since d¯f is linked to [R ℓ , M f ]. The main method in [32] is via creating a formula for Dixmier trace of |d¯f | n and using double operator integrals, which made extensive use of pseudodifferential calculus and the Fourier transform -in this way the proof was dependent on Fourier theory.