2005
DOI: 10.1002/qua.20647
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Quantum dynamics of relaxation of a pair of coupled Morse oscillators: Effects of mass and electrical asymmetries

Abstract: ABSTRACT:A multiconfiguration time-dependent Hartree method based recipe is used to study the role of mass and electrical asymmetry in controlling the quantum dynamics of relaxation of a locally excited OOH bond in a water molecule, modeled by a pair of interacting Morse oscillators. The fast periodic energy transfer between the two equivalent OOH bonds in HOOOH is replaced by a rather slow process when one of the H atom is replaced by a deuterium atom. Application of static electric field along the OOD bond i… Show more

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Cited by 3 publications
(1 citation statement)
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“…and H 2 O [75,76]. It is also used in the Peyrard-Bishop model to simulate the Hbond between the DNA base pair [77].…”
Section: Two-coupled Morse Oscillator Systemmentioning
confidence: 99%
“…and H 2 O [75,76]. It is also used in the Peyrard-Bishop model to simulate the Hbond between the DNA base pair [77].…”
Section: Two-coupled Morse Oscillator Systemmentioning
confidence: 99%