2017
DOI: 10.2139/ssrn.3066398
|View full text |Cite
|
Sign up to set email alerts
|

Quantum-Mechanical Analysis of the MO Method and VB Method from the Position of PQS

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2

Citation Types

0
2
0

Year Published

2019
2019
2019
2019

Publication Types

Select...
2

Relationship

0
2

Authors

Journals

citations
Cited by 2 publications
(2 citation statements)
references
References 0 publications
0
2
0
Order By: Relevance
“…But the data of photoelectron spectroscopy show that such a description does not correspond to reality. But it must be remembered that if the MO method is analyzed from the point of view of quantum mechanics, then it is also not true, since it contradicts the principle of quantum superposition [4].…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…But the data of photoelectron spectroscopy show that such a description does not correspond to reality. But it must be remembered that if the MO method is analyzed from the point of view of quantum mechanics, then it is also not true, since it contradicts the principle of quantum superposition [4].…”
Section: Resultsmentioning
confidence: 99%
“…Thus, both the MO theory and the hybridization theory are based on one fundamental assumption: the resulting wave function of a single-electron orbital (or MO, or hybrid AO) is a linear combination of single-electron atomic orbitals (or different atoms, or one atom). Therefore, the proof given about the contradiction of MO theory to the principle of quantum superposition is also correct for the theory of hybridization, since the principle of quantum superposition in any linear combination of AO prohibits obtaining a "new quality" (or MO, or hybridized AO) [4]. This strictly follows from the very principle of quantum superposition [7].…”
Section: Resultsmentioning
confidence: 99%