We analyze the quantum phase transition-like behavior in the lowest energy state of a two-site coupled atom-cavity system, where each cavity contains one atom but the total excitation number is not limited to two. Utilizing the variance of the total excitation number to distinguish the insulator and superfluid states, and the variance of the atomic excitation number to identify the polaritonic characteristics of these states, we find that the total excitation number plays a significant role in the lowest-energy-state phase transitions. In both the small hopping regime and the small atomfield interaction regime, we identify an interesting coexisting phase involving characteristics of both photonic superfluid and atomic insulator. For small hopping, we find that the signature of the photonic superfluid state becomes more pronounced with the increase in total excitation number, and that the boundaries of the various phases shift with respect to the case of N = 2. In the limit of small atom-field interaction, the polaritonic superfluid region becomes broader as the total excitation number increases. We demonstrate that the variance of the total excitation number in a single site has a linear dependence on the total excitation number in the large-detuning limit.