We study the sensitivity of a collisional single-atom probe for
ultracold gases. Inelastic spin-exchange collisions map information
about the gas temperature T or external magnetic field B onto the
quantum spin-population of single-atom probes, and previous work showed
enhanced sensitivity for short-time nonequilibrium spin dynamics [Phys.
Rev. X 10, 011018 (2020)]. Here, we numerically investigate the
steady-state sensitivity of such single-atom probes to various
observables. We find that the probe shows distinct sensitivity maxima in
the (B,T) parameter diagram, although the underlying spin-exchange rates
scale monotonically with temperature and magnetic field. In parameter
space, the probe generally has the largest sensitivity when sensing the
energy ratio between thermal energy and Zeeman energy in an externally
applied magnetic field, while the sensitivity to the absolute energy,
i.e., the sum of kinetic and Zeeman energy, is low. We identify the
parameters yielding sensitivity maxima for a given absolute energy,
which we can relate to a direct comparison of the thermal
Maxwell-Boltzmann distribution with the Zeeman-energy splitting. We
compare our equilibrium results to nonequilibrium experimental results
from a single-atom quantum probe, showing that the sensitivity maxima in
parameter space qualitatively prevail also in the nonequilibrium
dynamics, while a quantitative difference remains. Our work thereby
offers a microscopic explanation for the properties and performance of
this single-atom quantum probe, connecting thermodynamic properties to
microscopic interaction mechanisms. Our results pave the way for
optimization of quantum-probe applications in (B,T) parameter space
beyond the previously shown boost by nonequilibrium dynamics.