Motzkin spin chains are frustration-free models whose ground-state is a combination of Motzkin paths. The weight of such path contributions can be controlled by a deformation parameter t. As a function of the latter these models, beside the formation of domain wall structures, exhibit gapped Haldane topological orders with constant decay of the string order parameters for t < 1. A behavior compatible with a Berezinskii-KosterlitzThouless phase transition at t = 1 is also presented. By means of numerical calculations we show that the topological properties of the Haldane phases depend on the spin value. This allows to classify different kinds of hidden antiferromagnetic Haldane gapped regimes associated to nontrivial features like symmetry-protected topological order. Our results from one side allow to clarify the physical properties of Motzkin frustration-free chains and from the other suggest them as a new interesting and paradigmatic class of local spin Hamiltonians. [6] has been discovered for spin-1 XXZ Heisenberg chains. This has driven significant efforts to look for new kinds of models whose topological order can be described in terms of a SOP [7] motivating the discovery of the celebrated AffleckKennedy-Lieb-Tasaki (AKLT) model [8]. Although the argument of Haldane is given for integer spin chains, only integer spin XXZ-like and AKLT-like chains own topological HP and is therefore non-trivial to find and study new classes of Hamiltonians where HP emerges. Thanks to the strongest quantum "resource", namely the entanglement, spin models have also a fundamental role in the simulation of quantum logical gates for quantum computation [4]. For this reason finding and studying Hamiltonians with highly entangled spins is currently one of the most challenging and intriguing fields in quantum physics. In this direction local integer frustration-free spin Hamiltonians whose ground-state can be expressed as a combination of Motzkin paths [9] have been recently introduced [10,11]. Among others interesting aspects, their importance is given by the fact that they own a level of entanglement entropy which strongly exceeds the one exhibited by other previously known local models. Relevantly, also for half-integer spins, a similar class of Hamiltonians, the Fredkin spin chains, exhibiting the same features [12,13] has been introduced. In addition to their entanglement properties Motzkin chains own further very peculiar properties. Indeed, even if they are purely local models, for high spin values s (i.e., s ≥ 2) they behave as de facto long range Hamiltonians being able to violate cluster decomposition properties (CDP) and area law (AL) scaling DMRG local magnetization for a system of length 2n = 60 at different t deformation values S z i for c) s = 1 and d) s = 2. Lower panels: Thermodynamic limit of the gap ∆ = E1 − E0 as a function of t for e) s = 1 (red circles) and f) s = 2 (blue squares). The continuos lines are fitted with the form ∼ exp(−b/ √ tc − t) with tc = 1 and b a fitting parameter. The thermodynamic limit ...